化工新型材料

化工新型材料 ›› 2020, Vol. 48 ›› Issue (7) : 271-274. DOI: 10.19817/j.cnki.issn 1006-3536.2020.07.061

开发与应用

胺基酞菁/杂多酸荷移复合物的制备、表征及抑菌性能研究

尹彦冰, 张迅, 杨杭

作者信息 +

Preparation,characterization and bacteriostati property of amino phthalocyanine/heteropoly acid charge transfer complex

Yin Yanbing, Zhang Xun, Yang Hang

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文章历史 +

Received		Published
2019-03-19		2020-07-20
Issue Date	Revised Date
2022-11-01	2019-03-19

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摘要

以两种不同胺基取代的酞菁钴和两种Keggin型杂多酸为原料,N,N-二甲基甲酰胺为溶剂,在35℃下通过电荷转移的方式制得4种胺基酞菁/杂多酸荷移复合物。利用紫外-可见光谱、红外光谱对其结构进行了表征,利用热重分析对其热稳定性进行了考察;将4种复合物用于不同菌种的抑菌试验中,研究其抑菌性能。结果表明:产物是通过化学键键合所得的一种新型荷移复合物,且复合物热稳定性较好,从抑菌实验结果可知复合物α-四二甲胺基钴酞菁/磷钼钒杂多酸对枯草芽孢杆菌具有较好的抑制作用。

Abstract

Four amino phthalocyanine/heteropoly acid charge transfer complex were prepared by charge transfer process at 35℃,while two kinds of amino phthalocyanine and two Keggin-type heteropoly acids were used as raw materials,DMF as solvent.Structure of the complex were characterized by UV-visible spectroscopy and infrared spectroscopy,thermal stability were inspected by thermogravimetric analysi.The complex were applied in the antibacterial test of different strains to study their bacteriostati property.The results shown that the product was a novel charge-transfer complex connected by chemical bond,and the complex had good thermal stability.It can be seen that the complex α-tetramethylamino cobalt phthalocyanine/phosphomolybdate heteropoly acid had a good inhibitory effect on Bacillus subtilis.

关键词

胺基酞菁 / 杂多酸 / 荷移复合物 / 抑菌实验

Key words

amino phthalocyanine / heteropoly acid / charge transfer complex / bacteriostatic test

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胺基酞菁/杂多酸荷移复合物的制备、表征及抑菌性能研究[J]. 化工新型材料, 2020, 48(7): 271-274 DOI:10.19817/j.cnki.issn 1006-3536.2020.07.061

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